Chapter 12 · Liquids, Solids, and Intermolecular Forces

12.3Intermolecular Forces in Action: Surface Tension and Viscosity

9 min · two checks

Predict

Why does honey pour more slowly than water?

The idea

  • Define surface tension and viscosity.
  • Predict how temperature affects viscosity.

Surface tension is the energy cost of making more surface. Liquids with strong intermolecular forces — water, because of hydrogen bonding — have high surface tension. Detergents lower water’s surface tension by crowding the surface with molecules that do not hydrogen-bond as effectively. That helps water spread and wet a fabric instead of beading.

Viscosity is resistance to flow. Strong attractions, long tangled molecules, and low temperature all raise it. Motor oils are graded because viscosity changes with temperature; a winter oil has to stay fluid when kinetic energy is low. Surface tension and viscosity are both macroscopic hints about the same invisible attractions.

Keep these

  • High intermolecular forces → high surface tension.
  • Viscosity is resistance to flow and falls as temperature rises.
  • Surfactants lower surface tension.

Check yourself

1. Warming a thick oil makes it
2. Water’s unusually high surface tension is mainly due to