Chapter 8 · Quantities in Chemical Reactions

8.3Making Molecules: Mole-to-Mole Conversions

10 min · two checks

Predict

How many moles of H₂O form from 3.0 mol of H₂ in 2 H₂ + O₂ → 2 H₂O, if oxygen is plentiful?

The idea

  • Convert moles of one substance to moles of another with a coefficient ratio.
  • Write the ratio so units cancel.

The conversion factor is (coefficient of wanted) / (coefficient of given), in moles. From the water equation, mol H₂O = mol H₂ × (2 mol H₂O / 2 mol H₂). From combustion of methane, CH₄ + 2 O₂ → CO₂ + 2 H₂O, moles of oxygen required are twice the moles of methane. Write the factor explicitly. A bare multiplication by 2, with no labels, will be backwards half the time.

This step assumes the other reactant is available in excess, or that you were handed moles of the reactant you intend to run to completion. If both reactants are limited, you cannot convert from either one until you know which one runs out. That is the next major idea. Mole-to-mole is still the center of the map either way.

Keep these

  • Use coefficients as a mol-to-mol factor.
  • The factor is wanted over given.
  • This step assumes you know which reactant is fully used.

Worked path

How many moles of O₂ are needed to burn 0.80 mol of C₃H₈ completely? C₃H₈ + 5 O₂ → 3 CO₂ + 4 H₂O.

  1. Observe

    Given 0.80 mol C₃H₈. Want mol O₂.

Open the stoichiometry bench

Check yourself

1. For N₂ + 3 H₂ → 2 NH₃, moles of NH₃ from 4.5 mol H₂ (N₂ excess) are
2. The mole ratio of O₂ to CO₂ in C₃H₈ + 5 O₂ → 3 CO₂ + 4 H₂O is